Stress corrosion cracking in carbon steel dear all, we are inspecting a ammonia storage tank which was in service for more than 30 years. The harmful effect of grinding upon the resistance of steel to stresscorrosion cracking, very much in evidence in specimens with a martensitic structure, is negligible in the. The test results showed that aerial ammonia, instead of accelerating metal corrosion, reduced the. Stress corrosion cracking scc is a type of environmentallyassisted cracking eac, or the formation of cracks caused by various factors combined with the environment surrounding the pipeline. Oxygen in hightemperature environments can cause oxidation. The pitting inhibition of nitrate is dependent on the ph value of solutions, and nitrate is able to prevent the passivated iron surface from pitting attack only in acidic solutions. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. Corrosion is related to the susceptibility of the material to the environment, while stresses may be residual, external or. The carbon steel casings of heat recovery steam generators hrsgs in a cogeneration plant were found to have developed cracks that originated on the inside surfaces. Stress corrosion cracking scc in low and medium strength. Stresscorrosion cracking of steels in ammonia with. Corrosion of stainless steel 316 l in various aqueous salt solutions nawal muhammad dawood. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i.
Stress corrosion cracking in carbon steel bigpond, cracks seen are scc in carbon steel intergranular cracks along grain boundaries will come in welds hazparent plate where hardness is high or varied from other locations. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. The cracks are small at the surface but can be deep, worstcase going through the entire thickness of the metal. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al. For this test program, the steel coupons were made from 16 gage, carbon steel which were cut to 7 x 2. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. The failure was as a result of stress corrosion cracking scc of the cargo tank.
Despite its relatively limited corrosion resistance, carbon steel is used in large tonnages in marine applications, nuclear power and fossil fuel power plants, transportation, chemical processing, petroleum production and refining, pipelines, mining, construction. Stress corrosion cracking of carbon steel in nitrate and. Note that sodium hydroxide is commonly used at the savannah river site to adjust ph of the radioactive waste in order to inhibit the stress corrosion cracking effects of nitrate ion on steel in the large steel waste storage tanks. The stress corrosion cracking scc of carbon steel in nitratecontaining environments has been known for a long time and has become important in managing the integrity of aging underground. This type of failure is known as stress corrosion cracking, often abbreviated to scc. What causes stress corrosion cracking in pipelines. Electrochemical corrosion testing was the first phase of testing to identify the susceptibility to localized corrosion, especially pitting and scc for welded and unwelded samples. Although the c692 test method was designed to evaluate stress corrosion cracking of austenitic stainless steel, it was modified to use carbon steel coupons to make a quick, direct comparison of corrosion under insulation of various products.
Carbon steel, the most widely used engineering material, accounts for approximately 85%, of the annual steel production worldwide. Carbonate stress corrosion cracking acscc is a common problem in the oil and gas production, petroleum refining, and petrochemicalchemical processing industries. This recapitulation of experiences with stresscorrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. The effect of dissolved co 2 and o 2 on the corrosion of. A study was made to determine relevant growth data and to determine methods to prevent cracking.
Abstract the carbon steel casings of heat recovery steam generators hrsgs in a cogeneration plant were found to have developed cracks that. Stress corrosion cracking susceptibility of medium carbon steel in caustic and potash media a. Effect of temperature and concentration of ammonium. Effects of water on the stress corrosion cracking of carbon steel in ethanolic media fortunate moyo a research report submitted to the faculty of engineering and the built environment, university of the witwatersrand, johannesburg, in partial fulfilment of the requirements for the degree of master of science in engineering johannesburg, 20. Role of carbon in corrosion cracking of lowcarbon steels. The isothermal corrosion behavior of two stainless steels and carbon steel in mixtures of nano3 and kno3 has been evaluated to determine if the impurities found in commodity grades of alkali nitrates aggravate corrosivity as applicable to an advanced solar thermal. Certain aspects of the corrosion cracking of steels in nitrate solutions. Prevention of stress corrosion cracking of carbon steels. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking.
The stress corrosion cracking scc behaviour of medium carbon steel mcs in caustic soda, potash and a mixture of these reagents was studied by fracturing this material on a tensometer after every seven days of immersion in these media. The steels were subjected to aerated ammonium nitrate solutions of. Thermo12 gold with xox inhibits corrosion technical bulletin. Also, it readily combines with other elements to produce corrosive compounds. Parkins, the stress corrosion cracking of mild steel in nitrate solution, j. Stress corrosion cracking of an austenitic stainless steel in. Caustic stress corrosion cracking inspectioneering. Piping connected to safe end carbon steel sa 155 grade kfc60, cl1 feed water piping system. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments 1.
Stress corrosion cracking of an austenitic stainless steel. These cracks are not visible initially, but as time passes, these individual cracks may grow and forms colonies, and many of them join together to form longer cracks. Stress corrosion cracking control measures nist page. The resistance of inconel alloy 600 to stress corrosion cracking was correlated with carbon content, heat treatment, microstructure, and corrosion rate in nitric acid. Corrosion of stainlessand carbon steels in molten mixtures. Stress corrosion cracking of low carbon steel in methanol.
According to the equipment specifications, the welds were not given a. Pdf stress corrosion cracking of carbon steel in nitrate. Stresscorrosion cracking of low strength carbon steels in. More importantly, h 2 s can lead to catastrophic failures of carbon steel well tubing and other highpressure equipment through sulfide stress cracking. Five people were treated for inhalation injuries and released. Ranges of potential eh within which cracking is observed, as a function of naoh concentration for carbon steel in constant strain rate tests at boiling.
Acscc is a form of alkaline stress corrosion cracking that often occurs more aggressively at higher ph and high concentrations of carbonate solutions. The carbon steel casings of heat recovery steam generators hrsgs in a co generation plant were found to have developed cracks that originated on the. Crack development in carbon steel exposed to nitrate solution. If you you have temperatures above 150f,you could have stress corrosion cracking of 316 although unlikely below 200 f.
The astm standard specifies that the steel shall have the following chemical composition. Apart from the classically known hydroxide and nitrate media, stress corrosion cracking of such steels has been reported in a number of other environments, namely aqueous chloride, carbonate, phosphate, ammonia, coco 2h 2 o, high purity water containing oxygen, fuel ethanol and several. Carbonate stress corrosion cracking acscc inspectioneering. Ammonia stress corrosion cracking a mmonia stress corrosion cracking scc is the phenomena of cracks being formed in carbon steel in contact with ammonia.
Corrosion of carbon and stainless steels in flue gases from. Examination revealed one throughwall crack, as well as additional cracks that did not penetrate all the way through the metal. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking is a major issue for rcs system pipes particularly in the weld regions where it is connected to rpv nozzles through safe ends. Scc occurs as a result of a combination between corrosion and tensile stress. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Chloride corrosion of carbon steel pipe engineering. Nitrate greatly accelerates the general corrosion of iron in acidic solutions, but has slight influence on the general corrosion in neutral solutions. Cherepin, the role of hydrogen in corrosion cracking of reinforcing steel, fiz. When migrating the old forums over to our new forums we were unable to retain the identity of the authors, so the old posts will show up as anonymous.
Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. If this is a potable water as described,there is no reason to consider anything but carbon or galvanized steel. The stresscorrosion cracking of carbon steel in coc02h20. Stress corrosion cracking and localized corrosion of. Corrosion of carbon and stainless steels in flue gases. Nitrate stress corrosion cracking in waste heat recovery. Stainless steel specimens, on the other hand, showed some structural changes and varying degrees of intergranular attack. The information in this chart has been supplied by reputable sources and is to be used only as a guide in selecting equipment for appropriate chemical compatibility. Jun 09, 2014 avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments 1.
Whilst an accurate figure would be elusive to even the most rigorous rationale, it is fair to say that repairing the consequences of corrosion is a costly business. Chloride stress corrosion cracking in austenitic stainless. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Stress corrosion cracking in pipelines begins when small cracks develop on the external surface of buried pipelines. Influence of nitrate and chloride ions on the corrosion of. Stress corrosion cracking of steel in liquefied ammonia. Nitrate stress corrosion cracking of carbon steel equipment. Expanding the basic knowledge required for improved understanding of hydrogen sulfide h 2 s corrosion of mild steel is needed. Amine cracking is a form of stress corrosion cracking, which is related to alkaline and carbonate stress corrosion cracking. The dissolved carbon monoxide in the water forms an inhibitive layer on the surface of the steel. When it comes to even the most basic chemical descriptors of aqueous h 2 s systems such as h 2 s solubility, water chemistry, polymorphism of iron sulfide, the formation or dissolution of iron sulfide scale, and its protectiveness, many open questions persist and. The effect of varying the temperature and the concentration of ammonium nitrate solution on the stress corrosion cracking scc susceptibility of mild steel is studied.
Note that sodium hydroxide is commonly used at the savannah river site to adjust ph of the radioactive waste in order to inhibit the stress corrosion cracking effects of nitrate ion. From the results, the presence of nitrate inhibits the corrosion effect of the hydroxide alone. Role of carbon in corrosion cracking of lowcarbon steels in. The stress corrosion cracking scc of carbon steel in nitrate containing environments has been known for a long time and has become important in managing the integrity of aging underground radioactive waste storage tanks. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Effect of temperature and concentration of ammonium nitrate. Stainless steels in ammonia production nickel institute. Stress corrosion cracking scc is the formation and growth of crack. Chloride corrosion of carbon steel pipe engineering stack. Metabolites of an oil field sulfideoxidizing, nitrate. Hydrogen in itself not corrosive but can lead to blistering and embrittlement of steel.
Download citation nitrate stress corrosion cracking of carbon steel equipment the carbon steel casings of heat recovery steam generators hrsgs in a. Bent specimens of low carbon steel showed high susceptibility to stress corrosion in methanol containing 0. Corrosion behaviour of carbon steel in sodium nitrate solution corrosion behaviour of carbon steel in double distilled water, in the presence of various concentration of sodium nitrate sn have been evaluated by weight loss method, polarization study, ac impedance spectra, cyclic voltammetry, time vs current plots, and time vs potential plots. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Role of carbon in corrosion cracking of lowcarbon steels in nitrate solutions i. The stress corrosion cracking scc of carbon steel in nitrate containing environments has been known for a long time and has become important in managing the integrity of aging underground. Stress corrosion cracking in ammonia did not occur in steel specimens with fatigue precracks, due to a crevice corrosion attack.
Stress corrosion cracking scc of the welds in carbon steel transport and storage tanks for anhydrous ammonia has been experienced worldwide for the last 30 years. The stress corrosion cracking scc behavior of tank steel was investigated in a series of environments designed to simulate the chemistry of legacy nuclear weapons production waste being stored at the hanford tank reservation. Corrosion of stainless steel 316 l with time in various. Avoiding stress corrosion cracking of carbon low alloy and.
Stress corrosion cracking of carbon steel springerlink. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. The cost of stress corrosion cracking broad estimates put the cost of corrosion to 1 to 4 % of gnp in the usa. Four types of metal products uncoated 1010 carbon steel, galvanized steel, galvalume, and pure zinc were evaluated for weight losses and corrosion rates over a twomonth test period. Corrosion of stainlessand carbon steels in molten mixtures of. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. If the cl is present as hcl you have a problem that 316 wont solve. Amine cracking is often intertwined with wet hydrogen sulfide h 2 s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine treating systems. Increasing the plasticity of the steel causes a reduction in its proneness to stresscorrosion cracking, which does not occur at all in specimens tempered at 550c. Reservoir souring is difficult to control through chemical injection due to the expanse and remoteness of the biologically active zones within reservoirs. Under these passive conditions, however, carbon steels also can become susceptible to localized corrosion e. Stresscorrosion cracking of steel occurs in the coc02h20 system when these three environmental components are present together.
Corrosion behaviour of carbon steel in sodium nitrate solution. The following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Nitrate stress corrosion cracking of carbon steel equipment authors frank n. The initial rate of corrosion is high for nacl and kcl and the relative increase. Kristal, corrosion cracking of welded equipment of carbon steel in a sodium nitrate. The microstructure of the steel also appeared to be important. Thermodynamic study of hydrogen sulfide corrosion of mild. The effect of impurities, formic acid, water, and formaldehyde in methanol on the stress corrosion susceptibility of low carbon steel sheet was investigated by the constant strain rate test. A method for inhibiting stresscorrosion cracking of a steel pipeline transmitting gas under elevated pressure provided with an external protective coating and means for cathodic protection, and which is in contact with an environment containing at least one material selected from the group consisting of the alkali metal and alkaline earth metal hydroxides, carbonates. An increase in the temperature causes a decrease in the stress corrosion life.
Some of the stainless steels failed quickly by stress corrosion cracking when in contact with incinerator deposits under humid conditions at 170 f. Inhibition of stresscorrosion cracking of steel pipeline. Chloride stress corrosion cracking in austenitic stainless steel. The hrsgs receive hot exhaust gases from the primary gas turbines gts, which are fuelled with pipeline natural gas. Springs used in central office telephone equipment. It appears that the susceptibility in the range 368 k to 380 k was greater than at other temperatures. Borode school of chemical and metallurgical engineering, faculty of engineering and the built environment, university of the witwatersrand, johannesburg, south africa abstract. Elements such as molybdenum, manganese and chromium have a positive effect on the resistance to nitrate induced iga, saiga and rbon and copper are detrimental. Also, scc is a major issue for steam generator tube integrity in many us pwrs.
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